Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation.

نویسندگان

  • Motoki Toganoh
  • Takaaki Yamamoto
  • Takayoshi Hihara
  • Hisanori Akimaru
  • Hiroyuki Furuta
چکیده

A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

L-Proline catalyzed reaction of N-confused porphyrin and active methylene compounds.

Active methylene compounds such as acetone, butanone, cyclopentanone, nitromethane, malononitrile, ethyl 2-cyanoacetate, diethyl malonate, and ethyl acetylacetate react with the C3 position of N-confused porphyrin in the presence of L-proline in refluxing THF-EtOH affording a variety of N-confused porphyrin derivatives in moderate yield. L-Proline catalyzes the reaction facilitating the formati...

متن کامل

Ni(III) complex of an N-confused porphyrin inner C-oxide.

A novel, structurally characterized Ni(III) complex of an N-confused porphyrin inner C-oxide has been synthesized from the oxidation of a Ni(II) N-confused porphyrin using OsO4. Crystal data: C53H40N5NiO.CH2Cl2, monoclinic, space group P2/a (No. 13), a=21.229(1) A, b=8.6451(5) A, c=25.762(2) A, beta=93.004(3) degrees, V=4721.6(5) A3, and Z=4.

متن کامل

Comparative spectroscopic studies on porphyrin derivatives: electronic perturbation of N-confused and N-fused porphyrins.

N-confused and N-fused porphyrins revealed quite unique photophysical properties arising from their perturbed pi-conjugation pathways induced by structural modifications such as confusion and fusion of pyrrole rings compared with their parent porphyrin molecules.

متن کامل

Cooperation between metal and ligand in oxygen atom transport by N-confused porphyrin oxorhenium(V) complexes.

N-Confused porphyrin oxorhenium(V) complexes were prepared and their X-ray structures were elucidated. The oxorhenium(V) complexes can transfer oxygen atom from pyridine N-oxide to triphenylphosphine, in which unique cooperation between metal and ligand was observed.

متن کامل

Synthesis and reactions of the first fluoroalkylated Ni(II) N-confused porphyrins.

The first fluoroalkylated Ni(ii) N-confused porphyrins were synthesized with high regioselectivity and its further alkylation was studied.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 10 22  شماره 

صفحات  -

تاریخ انتشار 2012